Publications 2015-2019

Publications 2019

178) C. Dee, F. Zinna, W. R. Kitzmann, G. Pescitelli, K. Heinze*, L. Di Bari*, M. Seitz*,
Chem. Commun. 2019, 55, 13078–13081.
Strong Circularly Polarized Luminescence of an Octahedral Chromium(III) Complex
[DOI: 10.1039/c9cc06909g]

177) B. Sarkar, P. Vöhringer, K. Heinze, C. Förster,
Nachr. Chem. 2019, 67, 67–71.
Photochemie: Bindungen aktivieren und Redoxreaktionen
[DOI: 10.1002/nadc.20194090185]

176) S. Treiling, C. Wang, C. Förster, F. Reichenauer, J. Kalmbach, P. Boden, J. P. Harris, L. Carrella, E. Rentschler, U. Resch-Genger, C. Reber, M. Seitz, M. Gerhards, K. Heinze*,
Angew. Chem. 2019, 131, 18243–18253; Angew. Chem. Int. Ed. 2019, 58, 18075–18085.
Luminescence and Light-driven Energy and Electron Transfer from an Exceptionally Long-lived Excited State of a Non-innocent Chromium(III) Complex
[DOI: 10.1002/anie.201909325] [DOI: 10.1002/ange.201909325]
The paper is also highlighted as a cover in the journal Angewandte Chemie.

175) C. Förster, B. Sarkar, P. Vöhringer, K. Heinze*,
Nachr. Chem. 2019, 67, 54–59.
Photochemie: Licht und Leuchten bei 3d-Metallen
[DOI: 10.1002/nadc.20194089001]

174) J. Steube, L. Burkhardt, A. Päpcke, J. Moll, P. Zimmer, R. Schoch, C. Wölper, K. Heinze, S. Lochbrunner, M. Bauer*,
Chem. Eur. J. 2019, 25, 11826–11830.
Excited state kinetics of an air-stable cyclometalated iron(II) complex
[DOI: 10.1002/chem.201902488]
The paper is also highlighted as a cover in the journal Chemistry - A European Journal.

173) G. Bengasi, K. Baba, O. Back, G. Frache, K. Heinze*, N. D. Boscher*,
Chem. Eur. J. 2019, 25, 8313–8320.
Reactivity of Nickel(II) Porphyrins in oCVD Processes – Polymerisation, Intramolecular Cyclisation and Chlorination
[DOI: 10.1002/chem.201900793]

172) S. Lenz, H. Bamberger, P. P. Hallmen, Y. Thiebes, S. Otto, K. Heinze, J. van Slageren*,
Phys. Chem. Chem. Phys. 2019, 21, 6976–6983.
Chromium(III)-based potential molecular quantum bits with long coherence times
[DOI: 10.1039/C9CP00745H]

171) P. Veit, C. Volkert, C. Förster, V. Ksenofontov, S. Schlicher, M. Bauer, K. Heinze*,
Chem. Commun. 2019, 55, 4615–4618.
Gold(II) in Redox-Switchable Gold(I) Catalysis
[DOI: 10.1039/C9CC00283A]
The paper is also highlighted as a cover in the journal Chemical Communications. This article is part of the themed collection: Switchable Catalysis.

170) S. Preiß, A. Päpcke, L. Burkhardt, L. Großmann, S. Lochbrunner, M. Bauer, T. Opatz, K. Heinze*,
Gold(II) Porphyrins in Photoinduced Electron Transfer Reactions
Chem. Eur. J. 2019, 25, 5940–5949.
[DOI: 10.1002/chem.201900050]
This paper is included in the "Hot Topic Gold" issue.

169) O. Back, C. Förster, T. Basché, K. Heinze*,
Chem. Eur. J. 2019, 25, 6542–6552.
Alkali Blues: Blue-emissive alkali metal pyrrolates
[DOI: 10.1002/chem.201806103]
The paper is also highlighted as a cover in the journal Chemistry - A European Journal.

168) K. Baba, G. Bengasi, D. El Assad, P. Grysan, E. Lentzen, K. Heinze, G. Frache, N. D. Boscher*,
Eur. J. Org. Chem. 2019, 2368–2375.
Conductive Directly Fused Poly(Porphyrin) Coatings by Oxidative Chemical Vapour Deposition – from Single to Triple Fused
[DOI: 10.1002/ejoc.201900045]
The paper is also highlighted as a spotlight.

167) G. Bengasi, K. Baba, G. Frache, P. Gratia, K. Heinze, N. D. Boscher*,
Angew. Chem. 2019, 131, 2125–2130; Angew. Chem. Int. Ed. 2019, 58, 2103–2108.
Conductive fused porphyrin tapes on sensitive substrates by a Chemical Vapor Deposition approach
[DOI: 10.1002/anie.201814034]

166) C. Wang, S. Otto, M. Dorn, K. Heinze*, U. Resch-Genger*,
Anal. Chem. 2019, 91, 2337–2344.
Luminescent TOP Nanosensors for Simultaneously Measuring Temperature, Oxygen, and pH at a Single Excitation Wavelength
[DOI: 10.1021/acs.analchem.8b05060]

165) U. Basu, S. Otto, K. Heinze*, G. Gasser*, Eur. J. Inorg. Chem. 2019, 37–41.
Biological Evaluation of the NIR-Emissive Ruby Analogue [Cr(ddpd)2][BF4]3 as a Photodynamic Therapy Photosensitizer
[DOI: 10.1002/ejic.201801023]

Publications 2018

164) K. Heinze*, SciTech Europa Quarterly 2018, 28, 97.
Strong near-infrared emission with earth-abundant metal ions
[web link]

163) C. Förster, M. Dorn, T. Reuter, S. Otto, G. Davarci, T. Reich, L. Carrella, E. Rentschler, K. Heinze*, Inorganics 2018, 6, 86.
Ddpd as expanded terpyridine: dramatic effects of symmetry and electronic properties in first row transition metal complexes
[DOI: 10.3390/inorganics6030086]

162) C. Förster*, P. M. Becker, K. Heinze*,
Z. Anorg. Allg. Chem. 2018, 644, 1057–1063.
A ferrocenyl amino substituted stannylene as an intramolecular Fe→Sn Lewis adduct
[DOI: 10.1002/zaac.201800269]

161) S. Otto, J. Harris, K. Heinze*, C. Reber*,
Angew. Chem. 2018, 130, 11236–11240; Angew. Chem. Int Ed. 2018, 57, 11069–11073.
Molecular ruby under pressure
[DOI: 10.1002/ange.201806755] [DOI: 10.1002/anie.201806755]
This study was also highlighted at JGU press releases.

160) S. Otto, C. Förster, C. Wang, U. Resch-Genger*, K. Heinze*,
Chem. Eur. J. 2018, 24, 12555–12563.
A strongly luminescent chromium(III) complex acid
[DOI: 10.1002/chem.201802797]
The paper is also highlighted as a cover in the journal Chemistry - A- European Journal.

159) K. Hanauer, C. Förster, K. Heinze*,
Eur. J. Inorg. Chem. 2018, 3537–3547.
Redox-controlled stabilization of an open-shell intermediate in a bioinspired enzyme model
[DOI: 10.1002/10.1002/ejic.201800570]
The paper is also highlighted as a cover with an author profile and a press release in the European Journal of Inorganic Chemistry.

158) M. Dorn, K. Mack, L. M. Carrella, E. Rentschler, C. Förster*, K. Heinze*,
Z. Anorg. Allg. Chem. 2018, 644, 706–712.
Structure and electronic properties of an expanded terpyridine complex of nickel(II) [Ni(ddpd)2](BF4)2
[DOI: 10.1002/zaac.201800101]

157) S. Waniek, J. Klett*, C. Förster*, K. Heinze*,
Beilstein J. Org. Chem. 2018, 14, 1004–1015.
Polysubstituted Ferrocenes as Tunable Redox Mediators
Part of a "Thematic Series Electrosynthesis II".
[DOI: 10.3762/bjoc.14.86]

156) S. Otto, M. Dorn, C. Förster, M. Bauer, M. Seitz, K. Heinze*,
Coord. Chem. Rev. 2018, 359, 102–111.
Understanding and Exploiting Long-lived Near-infrared Emission of a Molecular Ruby (invited review)
Part of a "virtual special issue on the 22nd International Symposium on Photochemistry and Photochemistry of Coordination Compounds (ISPPCC)".
[DOI: 10.1016/j.ccr.2018.01.004]

155) C. Wang, S. Otto, M. Dorn, E. Kreidt, J. Lebon, L. Sršan, P. Di Martino-Fumo, M. Gerhards, U. Resch-Genger*, M. Seitz*, K. Heinze*,
Angew. Chem. 2018, 130, 1125–1130; Angew. Chem. Int. Ed. 2018, 57, 1112–1116.
Deuterated Molecular Ruby with Record Luminescence Quantum Yield
[DOI: 10.1002/ange.201711350] [DOI: 10.1002/anie.201711350]

Publications 2017

154) M. Lauck, C. Förster, K. Heinze*,
Organometallics 2017, 36, 4968–4978.
N-Cobaltocenium amide as reactive nucleophilic reagent for donor-acceptor bimetallocenes
[DOI: 10.1021/acs.organomet.7b00790]

153) K. Heinze*, Angew. Chem. 2017, 129, 16342–16350; Angew. Chem. Int. Ed. 2017, 56, 16126–16134.
The Quest for Mononuclear Gold(II) and its Potential Role in Photocatalysis and Drug Action (minireview)
[DOI: 10.1002/ange.201708349] [DOI: 10.1002/anie.201708349]

152) S. Otto, J. Moll, C. Förster, D. Geißler, C. Wang, U. Resch-Genger*, K. Heinze*, Eur. J. Inorg. Chem. 2017, 5033–5040.
Three in One Crystal: the Coordination Diversity of Zinc Polypyridine Complexes
[DOI: 10.1002/ejic.201700948]
Highlighted in the "EurJIC’s Dutch-German Virtual Issue".

151) K. Heinze*, S. Otto, GIT Labor-Fachzeitschrift 2017, 8, 32–34.
Temperaturmessung auf kleinster Skala

150) S. Otto, A. M. Nauth, E. Ermilov, N. Scholz, A. Friedrich, U. Resch-Genger, S. Lochbrunner*, T. Opatz*, K. Heinze*,
ChemPhotoChem 2017, 1, 344–349.
Photo-Chromium: Sensitizer for Visible Light-Induced Oxidative C-H Bond Functionalization – Electron or Energy Transfer?
[DOI: 10.1002/cptc.201700077]
This paper is highlighted as a cover article featuring a cover profile and as top contribution in Angew. Chem. 2017.

149) A. Schneeweis, A. Neidlinger, G. J. Reiss, W. Frank, K. Heinze, T. J. J. Müller*,
Org. Chem. Front. 2017, 4, 839–846.
Radical cation and dication of a 4H-dithieno[2,3-b:3',2'-e][1,4]-thiazine
[DOI: 10.1039/c7qo00188f]

148) S. Otto, N. Scholz, T. Behnke, U. Resch-Genger*, K. Heinze*,
Chem. Eur. J. 2017, 23, 12131–12135.
Thermo-Chromium: A Contactless Optical Molecular Thermometer
[DOI: 10.1002/chem.201701726]
This paper is part of the Special Issue 150 years of German Chemical Society GDCh.

147) A. K. C. Mengel, C. Bissinger, M. Dorn, O. Back, C. Förster, K. Heinze*,
Chem. Eur. J. 2017, 23, 7920–7931.
Boosting Vis/NIR Charge Transfer Absorptions of Iron(II) Complexes by N-Alkylation and N-Deprotonation in the Ligand Backbone
[DOI: 10.1002/chem.201700959]
The paper has been highlighted as a frontispiece and in the editorial.

146) S. Preiß, C. Förster, S. Otto, M. Bauer, P. Müller, D. Hinderberger, H. H. Haeri, L. Carella, K. Heinze*,
Nat. Chem. 2017, 9, 1249–1255.
Structure and Reactivity of a mononuclear gold(II) complex
[DOI: 10.1038/NCHEM.2836]
Click here for shared link access

145) M. Wang, N. D. Boscher, K. Heinze, K. K. Gleason*,
Adv. Funct. Mater. 2017, 27, 1606652.
Gas selective ultrathin organic covalent networks synthesized by iPECVD: Does the central metal ion matter?
[DOI: 10.1002/adfm.201606652]

144) M. Lauck, C. Förster, D. Gehrig, K. Heinze*,
J. Organomet. Chem. 2017, 847, 33–40.
Cobaltocenium Substituents as Electron Acceptors in Photosynthetic Model Dyads
(Special Issue on the occasion of John Gladysz's 65th birthday)
[DOI: 10.1016/j.jorganchem.2017.02.026]

143) K. Hanauer, M. T. Pham, C. Förster*, K. Heinze*,
Eur. J. Inorg. Chem. 2017, 433–445.
Solution Conformation and Self-Assembly of Ferrocenyl (Thio)Ureas
(Special Cluster Issue: The Multifaceted Chemistry of Ferrocene)
[DOI: 10.1002/ejic.201600918]

Publications 2016
142) T. Kienz, C. Förster, K. Heinze*,
Organometallics 2016, 35, 3681–3691.
Generation and Oligomerization of N-Ferrocenyl Ketenimines via Open-shell Intermediates
[DOI: 10.1021/acs.organomet.6b00619]

141) E. Jürgens, O. Back, J. Mayer, K. Heinze, D. Kunz*,
Z. Naturforsch. B, 2016, 71, 1011–1018.
Synthesis of copper(II) and gold(III) bis(NHC)-pincer complexes
[DOI: 10.1515/znb-2016-0158]

140) O. Back, J. Leppin, C. Förster, K. Heinze*,
Inorg. Chem. 2016, 55, 9653–9662.
Photo- and Redox Chemistry of an Unsymmetrical Bimetallic Copper(I) Complex
[DOI: 10.1021/acs.inorgchem.6b01400]

139) C. Kreitner, K. Heinze*,
Dalton. Trans. 2016, 45, 13631–13647.
Excited State Decay of Cyclometalated Polypyridine Ruthenium Complexes: Insight from Theory and Experiment (invited review)
[DOI: 10.1039/C6DT01989G]
The paper has been highlighted as a cover.
This paper has been highlighted in ChemInform 2016, 47 [DOI: 10.1002/chin.201642219]

138) P. Veit, C. Förster*, K. Heinze*,
Beilstein J. Org. Chem. 2016, 12, 1322–1333.
On the Mechanism of Imine Elimination from Fischer Tungsten Carbene Complexes
[DOI: 10.3762/bjoc.12.125]
Thematic Series: "Organometallic Chemistry" dedicated to the memory of Prof. Peter Hofmann.

137) R. Ragg, A. M. Schilmann, K. Korschelt, C. Wieseotte, M. Kluenker, M. Viel, L. Völker, S. Preiß, J. Herzberger, H. Frey, K. Heinze, P. Blümler, M. N. Tahir, F. Natalio, W. Tremel*,
J. Mater. Chem. B 2016, 4, 7423–7428.
Intrinsic Superoxide Dismutase Activity of MnO Nanoparticles Enhances Magnetic Resonance Imaging Contrast
[DOI: 10.1039/C6TB02078J]

136) A. Neidlinger, C. Förster, K. Heinze*,
Eur. J. Org. Chem. 2016, 4852–4864.
Conformational Switching of Multi-Responsive Ferrocenyl-Phenol Conjugates
[DOI: 10.1002/ejoc.201600774]

135) C. Kreitner, A. K. C. Mengel, T. K. Lee, W. Cho, K. Char, Y. S. Kang, K. Heinze*,
Chem. Eur. J. 2016, 22, 8915–8928.
Strongly Coupled Cyclometalated Ruthenium Triarylamine Chromophores as Sensitizers for DSSCs
[DOI: 10.1002/chem.201601001]

134) C. Kreitner, K. Heinze*,
Dalton Trans. 2016, 45, 5640–5658.
The photochemistry of mono- and dinuclear cyclometalated bis(tridentate)ruthenium(II) complexes: dual excited state deactivation and dual emission
[DOI: 10.1039/c6dt00384b]

133) P. Veit, E. Prantl, C. Förster*, K. Heinze*,
Organometallics 2016, 35, 249–257.
Competitive NH...Ru/Fe Hydrogen Bonding in Ferrocenyl Ruthenocenyl Tosyl Hydrazone
[DOI: 10.1021/acs.organomet.5b00963]

132) D. Siebler, K. Heinze*,
J. Organomet. Chem. 2016, 821, 19–24.
Conformational stability of oligoferrocene oligoamide foldamers
[DOI: 10.1016/j.jorganchem.2016.02.032]

131) A. Neidlinger, C. Förster, K. Heinze*,
Eur. J. Inorg. Chem. 2016, 1274–1286.
How Hydrogen Bonds Affect Reactivity and Intervalence Charge Transfer in Ferrocenium-Phenolate Radicals
[DOI: 10.1002/ejic.201501471]

130) A. Neidlinger, T. Kienz, K. Heinze*,
Organometallics 2015, 34, 5310–5320.
Spin Trapping of Carbon-Centered Ferrocenyl Radicals with Nitrosobenzene
[DOI: 10.1021/acs.organomet.5b00778]

129) S. Preiß, J. Melomedov, A. Wünsche von Leupoldt, K. Heinze*,
Chem. Sci. 2016, 7, 596–610.
Gold(III) tetraarylporphyrin amino acid derivatives: ligand or metal centred redox chemistry?
[DOI: 10.1039/c5sc03429a]
This publication has been highlighted in "Trendberichte aus der Anorganischen Chemie 2016 - Koordinationschemie und Bioanorganik": Nachr. Chem. Tech. 2017, 3, 245-254.

128) M. Schubert, P. Franzmann, A. Wünsche von Leupoldt, K. Koszinowski*, K. Heinze*, S. R. Waldvogel*,
Angew. Chem. 2016, 128, 1168–1172.
Angew. Chem. Int. Ed. 2016, 55, 1156–1159.
Over-oxidation as Key Step in the Mechanism of the MoCl5-mediated Dehydrogenative Coupling of Arenes
[DOI: 10.1002/anie.201508035] [DOI: 10.1002/ange.201508035]

127) N. D. Boscher, M. Wang, A. Perrotta, K. Heinze, M. Creatore, K. K. Gleason*,
Adv. Mater. 2016, 28, 7479–7484.
Metal organic covalent network chemical vapor deposition for gas separation
[DOI: 10.1002/adma.201601010]
The paper has been highlighted as a frontispiece.

Publications 2015

126) P. Veit, C. Förster*, S. Seibert, K. Heinze*,
Z. Anorg. Allg. Chem. 2015, 641, 2083–2092.
Preparation, properties and reactivity of (aminoferrocenyl)(ferrocenyl)carbene(pentacarbonyl)chromium(0) as bulky isolobal trimetallo-amide
[DOI: 10.1002/zaac.201500562]

125) S. Otto, M. Grabolle, C. Förster, C. Kreitner, U. Resch-Genger*, K. Heinze*,
Angew. Chem. 2015, 127, 11735–11739.
Angew. Chem. Int. Ed. 2015, 54, 11572–11576.
[Cr(ddpd)2]3+: a molecular, water-soluble, highly NIR-emissive ruby analogue
[DOI: 10.1002/anie.201504894] [DOI: 10.1002/ange.201504894]
The paper is selected as a Hot Paper.

124) C. Kreitner, E. Erdmann, W. W. Seidel, K. Heinze*,
Inorg. Chem. 2015, 54, 11088–11104.
Understanding the excited state behavior of cyclometalated bis(tridentate)ruthenium(II) complexes: a combined experimental and theoretical study
[DOI: 10.1021/acs.inorgchem.5b01151]
The paper has been highlighted as a cover.

123) K. Heinze*,
Coord. Chem. Rev. 2015, 300, 121–141.
Bioinspired Functional Analogues of the Active Site of Molybdenum Enzymes: Intermediates and Mechanisms (invited review)
[DOI: 10.1016/j.ccr.2015.04.010]

122) C. Förster, T. E. Gorelik, U. Kolb, V. Ksenofontov, K. Heinze*,
Eur. J. Inorg. Chem. 2015, 920–924.
Crystalline Non-equilibrium Phase of a Cobalt(II) Complex with Tridentate Ligands
[DOI: 10.1002/ejic.201403200]

121) A. K. C. Mengel, W. Cho, A. Breivogel, K. Char, Y. S. Kang, K. Heinze*,
Eur. J. Inorg. Chem. 2015, 3299–3306.
A Bis(tridentate)cobalt Polypyridine Complex as Mediator in Dye-Sensitized Solar Cells
[DOI: 10.1002/ejic.201500252]

120) C. Förster, K. Heinze*,
Z. Anorg. Allg. Chem. 2015, 641, 517–520.
The Crystal Structure of the THF Adduct of Monolithioferrocene
[DOI: 10.1002/zaac.201400548]
The paper has been highlighted as a cover.

119) C. Förster, P. Veit, V. Ksenofontov, K. Heinze*,
Chem. Commun. 2015, 51, 1514–1516.
Diferrocenyl tosyl hydrazone with an ultrastrong NHFe hydrogen bond as double click switch
[DOI: 10.1039/C4CC08868a]

118) J. Leppin, M. Schubert, S. R. Waldvogel, K. Heinze*,
Chem. Eur. J. 2015, 21, 4229–4232.
Initial radical cation pathway in the Mo2Cl10-mediated dehydrogenative arene coupling
[DOI: 10.1002/chem.201406522]

117) A. K. C. Mengel, C. Förster, A. Breivogel, K. Mack, J. R. Ochsmann, F. Laquai, V. Ksenofontov, K. Heinze*,
Chem. Eur J. 2015, 21, 704–714.
A Heteroleptic Push-Pull Substituted Iron(II) Bis(tridentate) Complex with Low Energy Charge Transfer States
[DOI: 10.1002/chem.201404955]