Publications 2010-2014

Publications 2014

116) C. Kreitner, M. Grabolle, U. Resch-Genger, K. Heinze*,
Inorg. Chem. 2014, 53, 12947–12961.
Dual emission and excited state mixed-valence in a quasi-symmetric dinuclear Ru-Ru complex
[DOI: 10.1021/ic5020362]
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115) J. Leppin, C. Förster, K. Heinze*,
Inorg. Chem. 2014, 53, 12416–12427.
Molybdenum Complex with Bulky Chelates as Functional Model for Molybdenum Oxidases
[DOI: 10.1002/ic501751p]
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114) P. Heier, N. D. Boscher, P. Choquet, K. Heinze*,
Inorg. Chem. 2014, 53, 11086–11095.
Dual Application of (Aqua)(Chlorido)(Porphyrinato)Chromium(III) as Hypersensitive Amine-Triggered ON Switch and for Dioxygen Activation
[DOI: 10.1021/ic501644z]
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113) A. Breivogel, C. Kreitner, K. Heinze*,
Eur. J. Inorg. Chem. 2014, 5468–5490.
Redox and Photochemistry of Bis(terpyridine)ruthenium(II) Amino Acids and their Amide Conjugates – from Understanding to Applications (invited review)
[DOI: 10.1002/ejic.201402466]
The review is among the EJIC most accessed articles in 08/2014.
This paper has been highlighted as top paper and as cover.
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112) J. Melomedov, J. R. Ochsmann, M. Meister, F. Laquai, K. Heinze*,
Eur. J. Inorg. Chem. 2014, 2902–2915.
Aminoferrocene and Ferrocene Amino Acid as Electron Donors in Modular Porphyrin-Ferrocene and Porphyrin-Ferrocene-Porphyrin Conjugates
[DOI: 10.1002/ejic.201402138]
This paper has been highlighted as top paper.
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111) A. Breivogel, S. Wooh, J. Dietrich, T. Y. Kim, Y. S. Kang, K. Char, K. Heinze*,
Eur. J. Inorg. Chem. 2014, 2720–2734.
Anchor-Functionalized Push-Pull-Substituted Bis(tridentate) Ruthenium(II) Polypyridine Chromophores: Photostability and Evaluation as Photosensitizers
[DOI: 10.1002/ejic.201402091]
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110) T. Kienz, C. Förster, K. Heinze*,
Organometallics 2014, 33, 4803–4812.
Impact of O->S exchange in ferrocenyl amides on structure and redoxchemistry
[DOI: 10.1021/om500052k]
This paper is part of the Organometallics Special Issue on Organometallic Electrochemistry.
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109) J. Melomedov, J. R. Ochsmann, M. Meister, F. Laquai, K. Heinze*,
Eur. J. Inorg. Chem. 2014, 1984–2001.
Tuning reductive and oxidative photoinduced electron transfer in amide linked anthraquinone-porphyrin-ferrocene architectures
[DOI: 10.1002/ejic.201400118]
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108) M. Schubert, J. Leppin, K. Wehming, D. Schollmeyer, K. Heinze*, S. R. Waldvogel*,
Angew. Chem. 2014, 126, 2527–2530.
Angew. Chem. Int. Ed. 2014, 53, 2494-2497
Powerful Fluoroalkoxy-Molybdenum(V) Reagent for the Selective Oxidative Arene Coupling Reaction
[DOI: 10.1002/anie.201309287] [DOI: 10.1002/ange.201309287]
This paper has been highlighted in ChemInform 2014, 45 [DOI: 10.1002/chin.201432106]
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107) J. Leppin, C. Förster, K. Heinze*,
Inorg. Chem. 2014, 53, 1039–1047.
Ligand dynamics of tert-butyl isocyanide oxido complexes of molybdenum(IV)
[DOI:10.1021/ic4025102]
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106) K. Hüttinger, C. Förster, K. Heinze*,
Chem. Commun. 2014, 50, 4285–4288.
Intramolecular electron transfer between molybdenum and iron mimicking bacterial sulphite dehydrogenase
[DOI: 10.1039/C3CC46919K]
The paper has been highlighted as a cover.
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105) A. Wünsche von Leupoldt, C. Förster, T. J. Fiedler, N. H. Bings, K. Heinze*,
Eur. J. Inorg. Chem. 2013, 6079–6090.
Proton and Electron Transfer to a Polymer-Supported Nitrido Molybdenum(VI) Complex
[DOI: 10.1002/ejic.201301156]
The paper has been highlighted as a cover.
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104) A. Breivogel, M. Park, D. Lee, S. Klassen, A. Kühnle, C. Lee, K. Char, K. Heinze*,
Eur. J. Inorg. Chem. 2014, 288–295.
Push-Pull Design of Bis(tridentate)ruthenium(II) Polypyridine Chromophores as Deep Red Light Emitters in Light-Emitting Electrochemical Cells
[DOI: 10.1002/ejic.201301226]
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103) P. Heier, T. Bohn, P. Choquet, N. D. Boscher*, K. Heinze*,
J. Mater. Chem. A, 2014, 2, 1560–1570.
New Class of Zn(II) and Cr(III) Porphyrins Incorporated into Porous Polymer Matrices via an Atmospheric Pressure Plasma Enhanced CVD to Form Gas Sensing Layers
[DOI:10.1039/C3TA13488A]
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Publications 2013

102) A. Breivogel, M. Meister, C. Förster, F. Laquai, K. Heinze*,
Chem. Eur. J. 2013, 19, 13745-13760.
Excited State Tuning of Bis(tridentate)ruthenium(II) Polypyridine Chromophores by Push-Pull Effects and Bite Angle Optimization – A Comprehensive Experimental and Theoretical Study
[DOI: 10.1002/chem.201302231]
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101) K. Heinze*, H. Lang*,
Organometallics 2013, 32, 5623-5625.
Ferrocene – Beauty and Function
[DOI: 10.1021/om400962w]
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100) A. Neidlinger, V. Ksenofontov, K. Heinze*,
Organometallics 2013, 32, 5955-5965.
Proton coupled electron transfer in ferrocenium phenolate radicals
[DOI: 10.1021/om400498h]
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99) N. D. Boscher*, T. Bohn, P. Heier, F. Moisy, B. Untereiner, K. Heinze, P. Choquet,
Sens. Actuators, B 2014, 191, 553-560.
Optical Sensing Responses of CrIIICl(TPP)(H2O)-Based Coatings Obtained by an
Atmospheric Pressure Plasma Method – Application to the Detection of Volatile Amines

[DOI: 10.1016/j.snb.2013.10.044]

98) K. Heinze*,
in Molecular Catalysts: Structure and Functional Design (Ed. L. H. Gade, P. Hofmann),
Wiley-VCH, 2014, p.423-452
ISBN: 978-3-527-33521-3
Solid phases as protective environments for biomimetic catalysts.
[DOI: 10.1002/9783527673278]
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97) J. Melomedov, A. Wünsche von Leupoldt, M. Meister, F. Laquai, K. Heinze*,
Dalton Trans. 2013, 42, 9727-9739.
Porphyrin Amino Acids – Amide Coupling, Redox and Photophysical Properties of Bis(porphyrin) amides
[DOI: 10.1039/c3dt50711d]
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96) J. Dietrich, A. Wünsche von Leupoldt, M. Grabolle, U. Resch-Genger, K. Heinze*,
Eur. J. Inorg. Chem. 2013, 3009-3019.
Thermal and Photoinduced Electron Transfer in Directional Bis(terpyridine) ruthenium(II) – (Bipyridine)platinum(II) Complexes
[DOI: 10.1002/ejic.201201531]
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95) L. zur Borg, A. L. Domanski, A. Breivogel, M. Bürger, R. Berger, K. Heinze*, R. Zentel*
J. Mater. Chem. C 2013, 1, 1223-1230.
Light-Induced Charge Separation in a Donor-Chromophore-Acceptor Nanocomposite
Poly[TPA-Ru(tpy)2]@ZnO

[DOI: 10.1039/c2tc00535b]
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94) D. Boscher*, D. Duday, P. Heier, K. Heinze, F. Hilt, P. Choquet,
Plasma Process. Polym. 2013, 10, 336-344.
Plasma polymer membranes for immobilising metalloporphyrins
[DOI: 10.1002/ppap.201200132]
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93) P. Heier, C. Förster, D. Schollmeyer, N. Boscher, P. Choquet, K. Heinze*,
Dalton Trans. 2013, 42, 906-917.
aa- and ab-Zinc-meso-A2B2-Tetraarylporphyrins with large optical response to triethylamine
(cover article)
[DOI: 10.1039/c2dt31943h]
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92) J. Dietrich, U. Thorenz, C. Förster, K. Heinze*,
Inorg. Chem. 2013, 51, 1248-1264.
Effects of Sequence, Connectivity and Counter Ions in New Amide-Linked Ru(tpy)2 – Re(bpy) Chromophores on Redox Chemistry and Photophysics
[DOI: 10.1021/ic301632y]
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91) C. Förster, K. Mack, L. M. Carrella, V. Ksenofontov, E. Rentschler, K. Heinze*,
Polyhedron 2013, 52, 576-581.
Coordination of expanded terpyridine ligands to cobalt
[DOI: 10.1016/j.poly.2012.08.008]
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90) N. D. Boscher*, D. Duday, P. Heier, K. Heinze, F. Hilt, P. Choquet,
Surf. Coat. Technol. 2013, 234, 48-52.
Atmospheric pressure plasma deposition of metalloporphyrins containing mesoporous membranes for gas sensing applications
[DOI: 10.1016/j.surfcoat.2012.12.034]
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Publications 2012

89) K. Mack, A. Wünsche von Leupoldt, C. Förster, M. Ezhevskaya, D. Hinderberger, K. W. Klinkhammer, K. Heinze*,
Inorg. Chem. 2012, 51, 7851-7858.
Effect of chelate ring expansion on Jahn-Teller distortion and Jahn-Teller dynamics in copper(II) complexes
[DOI: 10.1021/ic300929g]
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88) C. Förster, M. Kovacević, L. Barišić*, V. Rapić, K. Heinze*,
Organometallics 2012, 31, 3683-3694.
Ferrocenyl labeled sugar amino acids – conformation and properties
[DOI: 10.1021/om300174p]
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87) V. Gierz, J. Melomedov, C Förster, C. Deißler, F. Rominger, D. Kunz*, K. Heinze*,
Chem. Eur. J. 2012, 18, 10677-10688.
Consequences of the one-electron reduction and photoexcitation of unsymmetric bisimidazolium salts
[DOI: 10.1002/chem.201200323]
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86) K. Hüttinger, C. Förster, T. Bund, D. Hinderberger, K. Heinze*,
Inorg. Chem. 2012, 51, 4180-4192.
Stereochemical consequences of oxygen atom transfer and electron transfer in imido/oxido molybdenum(IV, V, VI) complexes with two unsymmetric bidentate ligands
[DOI: 10.1021/ic202588u]
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85) H. Huesmann, C. Förster, D. Siebler, T. Gasi, K. Heinze*,
Organometallics 2011, 31, 413-427.
Amide-linked Heterobi- and Heterotermetallocenes with Very Low HOMO-LUMO Gaps
[DOI: 10.1021/om201007g]
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Publications 2011

84) K. Heinze*, K. Hüttinger, D. Siebler,
in Modeling of Molecular Properties (Ed. P. Comba), Wiley-VCH, 2011
Elucidation of the conformational freedom of ferrocene amino acid (bio-)conjugates – a complementary theoretical and experimental approach
ISBN-10: 3-527-33021-6
This paper has been highlighted in ChemInform 2012, 43 [DOI: 10.1002/chin.201217252]
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83) D. Siebler, C. Förster, K. Heinze*,
Abstracts of Papers 2011, 241st ACS National Meeting, Anaheim, CA, US (INOR-869)
[abstract]

82) D. Siebler, C. Förster, T. Gasi, K. Heinze*,
Organometallics 2011, 30, 313-327.
Biferrocene amino acid – A ferrocenylogoue of ferrocene amino acid: Synthesis, Crosslinking, and Redox Chemistry
[DOI: 10.1021/om1010808]
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81) A. Breivogel, K. Hempel, K. Heinze*,
Inorg. Chim. Acta 2011, 374, 152-162.
Dinuclear Bis(terpyridine)ruthenium(II) Complexes by Amide Coupling of Ruthenium Amino Acids: Synthesis and Properties
[DOI: 10.1016/j.ica.2011.03.046]
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80) D. Siebler, C. Förster, K. Heinze*,
Dalton Trans. 2011, 40, 3558-3575.
Redox-responsive Organometallic Foldamers from Ferrocene Amino Acid: Solid-Phase Synthesis, Secondary Structure and Mixed-Valence Properties
[DOI: 10.1039/c0dt01528h]
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79) D. Siebler, M. Linseis, T. Gasi, L. M. Carrella, R. F. Winter, C. Förster, K. Heinze*,
Chem. Eur. J. 2011, 17, 4540-4551.
Oligonuclear Ferrocene Amides: Mixed-valent Peptides and Potential Redox-switchable Foldamers
[DOI: 10.1002/chem.201002101]
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78) R. André, F. Natálio, M. Humanes, J. Leppin, K. Heinze, R. Wever, H.-C. Schröder, W. E. G. Müller, W. Tremel*,
Adv. Funct. Mater. 2011, 21, 501-509.
V2O5 Nanowires with an Intrinsic Peroxidase-like Activity
[DOI: 10.1002/adfm.201001302]
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Publications 2010

77) W. Liu, K. Heinze*,
Dalton Trans. 2010, 39, 9554-9564.
Rhenium(I) and Platinum(II) Complexes with Diimine Ligands Bearing Acidic Phenol Substituents: Hydrogen-Bonding, Acid-Base Chemistry and Optical Properties
[DOI: 10.1039/c0dt00393j]
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76) A. Breivogel, C. Förster, K. Heinze*,
Inorg. Chem. 2010, 49, 7052-7056.
A Heteroleptic Bis(tridentate)ruthenium(II) Polypyridine Complex with Improved Photophysical Properties and Integrated Functionalizability
[DOI: 10.1021/ic1007236]
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75) D. Siebler, C. Förster, K. Heinze*,
Eur. J. Inorg. Chem. 2010, 3986-3992.
"Tail-tail" dimerization of ferrocene amino acid derivatives
[DOI: 10.1002/ejic.201000384]
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74) C. Förster, D. Siebler, K. Heinze*,
Acta Cryst. 2010, C66, m235-m237.
Ferrocene compounds. Methyl-1'-aminoferrocene-1-carboxylic acid
[DOI: 10.1107/S0108270110025746]
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73) D. Siebler, C. Förster, T. Gasi, K. Heinze*,
Chem. Commun. 2010, 4490-4492.
Formation and Mixed-valent Behaviour of a substituted Tetraferrocenylstannane
[DOI: 10.1039/c0cc00227e]
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72) K. Heinze*, A. Fischer,
Eur. J. Inorg. Chem. 2010, 1939-1947.
Oxido-Molybdenum(IV), -(V), -(VI) Complexes with Relevance to Molybdenum Enzymes: Oxygen Atom Transfer, Redox Chemistry and EPR Spectroscopy
[DOI: 10.1002/ejic.200901035]
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71) M. Cakic Semencic, K. Heinze*, C. Förster, V. Rapic*,
Eur. J. Inorg. Chem. 2010, 1089-1097.
Bioconjugates of 1’-Aminoferrocene-1-carboxylic Acid with (S)-3-Amino-2-methylpropanoic Acid and L-Alanine
[DOI: 10.1002/ejic.200901146]
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70) D. Siebler, C. Förster, K. Heinze*,
Eur. J. Inorg. Chem. 2010, 523-527.
Molecular Multi-Wavelength Optical Anion Sensors
[DOI: 10.1002/ejic.200901051]
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69) J. Lapic, S. Djakovic, M. Cetina, K. Heinze*, V. Rapic*,
Eur. J. Inorg. Chem. 2010, 106-114.
C2 Symmetric Ferrocene Bisureido Peptides: Synthesis, Conformation and Solid State Structure
[DOI: 10.1002/ejic.200900679]
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