Collaborations

Coordinated Research Programs (in alphabetical order)

• CINEMA, Center of INnovative and Emerging MAterials, JGU Mainz

• COST SIPs, COST Action CM1302 European Network on Smart Inorganic Polymers (SIPs)

• ELYSION, Advanced Lab for Electrochemistry and Electroorganic Synthesis, JGU Mainz

• IRTG, International Research Training Group 1404 - Self-organized Materials for Optoelectronics

• LESSING, Light-inducEd Sensitizing, Switching and ImagiNG

• LCRMC, DFG Priority Program Light controled reactivity of metal complexes

• MAINZ, Graduate School of Excellence Materials Science in Mainz

Current Collaborations (in alphabetical order)

• Prof. Dr. Matthias Bauer, Department of Chemistry, University of Paderborn
  S.Preiß, C. Förster, S. Otto, M. Bauer, P. Müller, D. Hinderberger, H. H. Haeri, L. Carella, K. Heinze*, Nat. Chem. 2017, 9, 1249-1255 "Structure and Reactivity of a mononuclear gold(II) complex" [DOI: 10.1038/NCHEM.2836]
  S. Otto, M. Dorn, C. Förster, M. Bauer, M. Seitz, K. Heinze*, Coord. Chem. Rev. 2018, 359, 102-111 "Understanding and Exploiting Long-lived Near-infrared Emission of a Molecular Ruby" (invited review) [DOI: 10.1016/j.ccr.2018.01.004]

• Prof. Dr. Kookheon Char, School of Chemical & Biological Engineering, Seoul National University, Seoul, Korea
  C. Kreitner, A. K. C. Mengel, T. K. Lee, W. Cho, K. Char, Y. S. Kang, K. Heinze*, Chem. Eur. J. 2016, 22, 8915-8928 "Strongly Coupled Cyclometalated Ruthenium Triarylamine Chromophores as Sensitizers for DSSCs" [DOI: 10.1002/chem.201601001]
  A. Breivogel, M. Park, D. Lee, S. Klassen, A. Kühnle, C. Lee, K. Char, K. Heinze*, Eur. J. Inorg. Chem. 2014, 288-295 "Push-Pull Design of Bis(tridentate)ruthenium(II) Polypyridine Chromophores as Deep Red Light Emitters in Light-Emitting Electrochemical Cells" [DOI: 10.1002/ejic.201301226]
  A. Breivogel, S. Wooh, J. Dietrich, T. Y. Kim, Y. S. Kang, K. Char, K. Heinze*, Eur. J. Inorg. Chem. 2014, 2720–2734 "Anchor-Functionalized Push-Pull-Substituted Bis(tridentate) Ruthenium(II) Polypyridine Chromophores: Photostability and Evaluation as Photosensitizers" [DOI: 10.1002/ejic.201402091]

• Prof. Dr. Gilles Gasser, Laboratory for Inorganic Chemical Biology, PSL Research University, Chimie ParisTech

U. Basu, S. Otto, K. Heinze*, G. Gasser*, Eur. J. Inorg. Chem. 2018, in press. "Biological Evaluation of the NIR-Emissive Ruby Analogue [Cr(ddpd)₂][BF₄]₃ as a Photodynamic Therapy Photosensitizer"

• Prof. Dr. Markus Gerhards, Institute of Physical Chemistry, Technical University Kaiserlautern
  C. Wang, S. Otto, M. Dorn, E. Kreidt, J. Lebon, L. Sršan, P. Di Martino-Fumo, M. Gerhards, U. Resch-Genger*, M. Seitz*, K. Heinze*, Angew. Chem. Int. Ed. 2018, 57, 1112-1116 "Deuterated Molecular Ruby with Record Luminescence Quantum Yield" [DOI: 10.1002/ange.201711350]

• Prof. Dr. Dariush Hinderberger, Institute of Physical Chemistry, University of Halle
  K. Hüttinger, C. Förster, T. Bund, D. Hinderberger, K. Heinze*, Inorg. Chem. 2012, 51, 4180-4192 "Stereochemical consequences of oxygen atom transfer and electron transfer in imido/oxido molybdenum(IV, V, VI) complexes with two unsymmetric bidentate ligands" [DOI: 10.1021/ic202588u]
  K. Mack, A. Wünsche von Leupoldt, C. Förster, M. Ezhevskaya, D. Hinderberger, K. W. Klinkhammer, K. Heinze*, Inorg. Chem. 2012, 51, 7851-7858 "Effect of chelate ring expansion on Jahn-Teller distortion and Jahn-Teller dynamics in copper(II) complexes" [DOI: 10.1021/ic300929g]

• Prof. Dr. Changhee Lee, School of Electrical Engineering and Computer Science, Seoul National University, Seoul, Korea
  A. Breivogel, M. Park, D. Lee, S. Klassen, A. Kühnle, C. Lee, K. Char, K. Heinze*, Eur. J. Inorg. Chem. 2014, 288-295 "Push-Pull Design of Bis(tridentate)ruthenium(II) Polypyridine Chromophores as Deep Red Light Emitters in Light-Emitting Electrochemical Cells" [DOI: 10.1002/ejic.201301226]

• Prof. Dr. Doris Kunz, Department of Inorganic Chemistry, University of Tübingen
  E. Jürgens, O. Back, J. Mayer, K. Heinze, D. Kunz*, Z. Naturforsch. B 2016, 71, 1011-1018 "Synthesis of copper(II) and gold(III) bis(NHC)-pincer complexes" [DOI: 10.1515/znb-2016-0158]
  V. Gierz, J. Melomedov, C. Förster, C. Deißler, F. Rominger, D. Kunz*, K. Heinze*, Chem. Eur. J. 2012, 18, 10677-10688 "Consequences of the one-electron reduction and photoexcitation of unsymmetric bisimidazolium salts" [DOI: 10.1002/chem.201200323]

• Prof. Dr. Stefan Lochbrunner, Institute of Physics, University of Rostock
  S. Otto, A. M. Nauth, E. Ermilov, N. Scholz, A. Friedrich, U. Resch-Genger, S. Lochbrunner*, T. Opatz*, K. Heinze*, ChemPhotoChem 2017, 1, 344-349 "Photo-Chromium: Sensitizer for Visible Light-Induced Oxidative C-H Bond Functionalization – Electron or Energy Transfer?" [DOI: 10.1002/cptc.201700077]

• Luxembourg Institute of Science and Technology, Dr. Patrick Choquet, Dr. Nicolas Boscher, Belvaux, Luxembourg
  M. Wang, N. D. Boscher, K. Heinze, K. K. Gleason*, Adv. Funct. Mater. 2017, 27, 1606652 "Gas selective ultrathin organic covalent networks synthesized by iPECVD: Does the central metal ion matter?" [DOI: 10.1002/adfm.201606652]
  N. D. Boscher, M. Wang, A. Perrotta, K. Heinze, M. Creatore, K. K. Gleason*, Adv. Mater. 2016, 28, 7479-7484 "Metal organic covalent network chemical vapor deposition for gas separation" [DOI: 10.1002/adma.201601010]
  N. D. Boscher*, T. Bohn, P. Heier, F. Moisy, B. Untereiner, K. Heinze, P. Choquet, Sens. Actuators, B 2014, 191, 553-560 "Optical Sensing Responses of Cr^IIICl(TPP)(H₂O)-Based Coatings Obtained by an Atmospheric Pressure Plasma Method – Application to the Detection of Volatile Amines" [DOI: 10.1016/j.snb.2013.10.044]
  N. D. Boscher*, D. Duday, P. Heier, K. Heinze, F. Hilt, P. Choquet, Surf. Coat. Technol., 2013, 234, 48-52 "Atmospheric pressure plasma deposition of metalloporphyrins containing mesoporous membranes for gas sensing applications" [DOI: 10.1016/j.surfcoat.2012.12.034]
  N. D. Boscher*, D. Duday, P. Heier, K. Heinze, F. Hilt, P. Choquet, Plasma Process. Polym. 2013, 10, 336-344 "Plasma polymer membranes for immobilising metalloporphyrins" [DOI:10.1002/ppap.201200132]
  P. Heier, C. Förster, D. Schollmeyer, N. Boscher, P. Choquet, K. Heinze*, Dalton Trans., 2013, 42, 906-917 "alpha-alpha- and alpha-beta-Zinc-meso-A₂B₂-Tetraarylporphyrins with large optical response to triethylamine" [DOI: 10.1039/c2dt31943h]

• Prof. Dr. Thomas J. J. Müller, Department of Organic Chemistry, University of Düsseldorf
  A. Schneeweis, A. Neidlinger, G. J. Reiss, W. Frank, K. Heinze, T. J. J. Müller*, Org. Chem. Front. 2017, 4, 839-846 "Radical cation and dication of a 4H-dithieno[2,3-b:3',2'-e][1,4]-thiazine" [DOI: 10.1039/c7qo00188f]

• Prof. Dr. Patrick Nürnberger, Institute of Physical Chemistry, University of Bochum

• Prof. Dr. Till Opatz, Institute of Organic Chemistry, University of Mainz
  S. Otto, A. M. Nauth, E. Ermilov, N. Scholz, A. Friedrich, U. Resch-Genger, S. Lochbrunner*, T. Opatz*, K. Heinze*, ChemPhotoChem 2017, 1, 344-349 "Photo-Chromium: Sensitizer for Visible Light-Induced Oxidative C-H Bond Functionalization – Electron or Energy Transfer?" [DOI: 10.1002/cptc.201700077]

• Dr. Ute Resch-Genger, Federal Institute for Materials Research and Testing, BAM, Berlin
  C. Wang, S. Otto, M. Dorn, E. Kreidt, J. Lebon, L. Sršan, P. Di Martino-Fumo, M. Gerhards, U. Resch-Genger*, M. Seitz*, K. Heinze*, Angew. Chem. Int. Ed. 2018, 57, 1112-1116 "Deuterated Molecular Ruby with Record Luminescence Quantum Yield" [DOI: 10.1002/ange.201711350] [DOI: 10.1002/anie.201711350]
  S. Otto, N. Scholz, T. Behnke, U. Resch-Genger*, K. Heinze*, Chem. Eur. J. 2017, 23, 12131-12135. "Thermo-Chromium: A Contactless Optical Molecular Thermometer" [DOI: 10.1002/chem.201701726]
  S. Otto, M. Grabolle, C. Förster, C. Kreitner, U. Resch-Genger*, K. Heinze*, Angew. Chem. 2015, 127, 11735-11739 "[Cr(ddpd)₂]³⁺: a molecular, water-soluble, highly NIR-emissive ruby analogue" [DOI: 10.1002/anie.201504894] [DOI: 10.1002/ange.201504894]
  C. Kreitner, M. Grabolle, U. Resch-Genger, K. Heinze*, Inorg. Chem. 2014, 53, 12947-12961 "Dual emission and excited state mixed-valence in a quasi-symmetric dinuclear Ru-Ru complex" [DOI: 10.1002/ic5020362]
  J. Dietrich, A. Wünsche von Leupoldt, M. Grabolle, U. Resch-Genger, K. Heinze*, Eur. J. Inorg. Chem. 2013, 3009-3019 "Thermal and Photoinduced Electron Transfer in Directional Bis(terpyridine)ruthenium(II) – (Bipyridine)platinum(II) Complexes" [DOI:10.1002/ejic.201201531]

• Prof. Dr. Wolfram W. Seidel, Department of Inorganic Chemistry, University of Rostock
  C. Kreitner, E. Erdmann, W. W. Seidel, K. Heinze*, Inorg. Chem. 2015, 54, 11088-11104 "Understanding the excited state behavior of cyclometalated bis(tridentate)ruthenium(II) complexes: a combined experimental and theoretical study" [DOI: 10.1021/ic5b01151]

• Prof. Dr. Michael Seitz, Institute of Inorganic Chemistry, University of Tübingen
  S. Otto, M. Dorn, C. Förster, M. Bauer, M. Seitz, K. Heinze*, Coord. Chem. Rev. 2018, 359, 102-111 "Understanding and Exploiting Long-lived Near-infrared Emission of a Molecular Ruby" (invited review) [DOI: 10.1016/j.ccr.2018.01.004]
  C. Wang, S. Otto, M. Dorn, E. Kreidt, J. Lebon, L. Sršan, P. Di Martino-Fumo, M. Gerhards, U. Resch-Genger*, M. Seitz*, K. Heinze*, Angew. Chem. Int. Ed. 2018, 57, 1112-1116 "Deuterated Molecular Ruby with Record Luminescence Quantum Yield" [DOI: 10.1002/ange.201711350] [DOI: 10.1002/anie.201711350]

• Prof. Dr. Siegfried R. Waldvogel, Institute of Organic Chemistry, University of Mainz
  M. Schubert, P. Franzmann, A. Wünsche von Leupoldt, K. Koszinowski*, K. Heinze*, S. R. Waldvogel*, Angew. Chem. 2016, 128, 1168-1172 "Over-oxidation as Key Step in the Mechanism of the MoCl₅-mediated Dehydrogenative Coupling of Arenes" [DOI: 10.1002/anie.201508035] [DOI: 10.1002/ange.201508035]
  J. Leppin, M. Schubert, S. R. Waldvogel, K. Heinze*, Chem. Eur. J. 2015, 21, 4229-4232 "Initial radical cation pathway in the Mo₂Cl₁₀-mediated dehydrogenative arene coupling" [DOI: 10.1002/chem.201406522]
  M. Schubert, J. Leppin, K. Wehming, D. Schollmeyer, K. Heinze*, S. R. Waldvogel*, Angew. Chem. 2014, 126, 2527-2530 "Powerful Fluoroalkoxy-Molybdenum(V) Reagent for the Selective Oxidative Arene Coupling Reaction" [DOI: 10.1002/anie.201309287] [DOI: 10.1002/ange.201309287]

Former fruitful Collaborations (in alphabetical order)

• Prof. Dr. Nicolas H. Bings, Institute of Inorganic Chemistry, University of Mainz
  A. Wünsche von Leupoldt, C. Förster, T. J. Fiedler, N. H. Bings, K. Heinze*, Eur. J. Inorg. Chem. 2013, 6079-6090 "Proton and Electron Transfer to a Polymer-Supported Nitrido Molybdenum(VI) Complex" [DOI: 10.1002/ejic.201301156]

• Prof. Dr. Malcolm Chisholm, Ohio State University, Columbus, Ohio, USA
  M. H. Chisholm*, C. M. Hadad, K. Heinze, K. Hempel, N. Singh, S. Vyas, J. Cluster Sci. 2008, 19, 209-218 "[Bis(trispivalatodimolybdenum(II))-µ- bis(4'-carboxylato-2,2':6',2''-terpyridine)Ruthenium(II)](2+) tetrafluoroborate. Preparation, Electronic Structure and Physical Properties" [DOI: 10.1007/s10876-007-0167-0]

• Prof. Dr. Karl Klinkhammer, Department of Inorganic Chemistry, University of Mainz
  K. Mack, A. Wünsche von Leupoldt, C. Förster, M. Ezhevskaya, D. Hinderberger, K. W. Klinkhammer, K. Heinze*, Inorg. Chem. 2012, 51, 7851-7858 "Effect of chelate ring expansion on Jahn-Teller distortion and Jahn-Teller dynamics in copper(II) complexes" [DOI: 10.1021/ic300929g]

• Dr. Ute Kolb, Institute of Physical Chemistry, University of Mainz
  C. Förster, T. E. Gorelik, U. Kolb, V. Ksenofontov, K. Heinze*, Eur. J. Inorg. Chem. 2015, 920-924 "Crystalline Non-equilibrium Phase of a Cobalt(II) Complex with Tridentate Ligands" [DOI: 10.1002/ejic.201403200]

• Prof. Dr. Angelika Kühnle, Institute of Physical Chemistry, University of Mainz
  A. Breivogel, M. Park, D. Lee, S. Klassen, A. Kühnle, C. Lee, K. Char, K. Heinze*, Eur. J. Inorg. Chem. 2014, 288-295 "Push-Pull Design of Bis(tridentate)ruthenium(II) Polypyridine Chromophores as Deep Red Light Emitters in Light-Emitting Electrochemical Cells" [DOI: 10.1002/ejic.201301226]

• Prof. Dr. Frederic Laquai, Max Planck Institute for Polymer Research, Mainz, now at KAUST
  J. Melomedov, J. R. Ochsmann, M. Meister, F. Laquai, K. Heinze*, Eur. J. Inorg. Chem. 2014, 2902-2915 "Aminoferrocene and Ferrocene Amino Acid as Electron Donors in Modular Porphyrin-Ferrocene and Porphyrin-Ferrocene-Porphyrin Conjugates" [DOI: 10.1002/ejic.201402138]
  J. Melomedov, J. R. Ochsmann, M. Meister, F. Laquai, K. Heinze*, Eur. J. Inorg. Chem. 2014, 1984–2001 "Tuning reductive and oxidative photoinduced electron transfer in amide linked anthraquinone-porphyrin-ferrocene architectures" [DOI: 10.1002/ejic.201400118]
  A. Breivogel, M. Meister, C. Förster, F. Laquai, K. Heinze*, Chem. Eur. J. 2013, 19, 13745-13760 "Excited State Tuning of Bis(tridentate)ruthenium(II) Polypyridine Chromophores by Push-Pull Effects and Bite Angle Optimization – A Comprehensive Experimental and Theoretical Study" [DOI: 10.1002/chem.201302231]
  J. Melomedov, A. Wünsche von Leupoldt, M. Meister, F. Laquai, K. Heinze*, Dalton Trans. 2013, 42, 9727-9739 "Porphyrin Amino Acids – Amide Coupling, Redox and Photophysical Properties of Bis(porphyrin) amides" [DOI: 10.1039/c3dt50711d]

• Prof. Dr. Vladimir Rapic, Faculty of Food and Biotechnology, Zagreb, Croatia
  C. Förster, M. Kovacevic, L. Barišic*, V. Rapic, K. Heinze*, Organometallics 2012, 31, 3683-3694 "Ferrocenyl labeled sugar amino acids – conformation and properties" [DOI: 10.1021/om300174p]
  M. Cakic Semencic, K. Heinze*, C. Förster, V. Rapic*, Eur. J. Inorg. Chem. 2010, 1089-1097 "Bioconjugates of 1’-Aminoferrocene-1-carboxylic Acid with (S)-3-Amino-2-methylpropanoic Acid and L-Alanine" [DOI: 10.1002/ejic.200901146]

• Prof. Dr. Eva Rentschler, Institute of Inorganic Chemistry, University of Mainz
  C. Förster, K. Mack, L. M. Carrella, V. Ksenofontov, E. Rentschler, K. Heinze*, Polyhedron 2013, 52, 576-581 "Coordination of expanded terpyridine ligands to cobalt" [DOI: 10.1016/j.poly.2012.08.008]

• Prof. Dr. Wolfgang Tremel, Institute of Inorganic Chemistry, University of Mainz
  R. André, F. Natálio, M. Humanes, J. Leppin, K. Heinze, R. Wever, H.-C. Schröder, W. E. G. Müller, W. Tremel*, Adv. Funct. Mater. 2011, 21, 501-509 "V₂O₅ Nanowires with an Intrinsic Peroxidase-like Activity" [DOI: 10.1002/adfm.201001302]
  R. Ragg, A. M. Schilmann, K. Korschelt, C. Wieseotte, M. Kluenker, M. Viel, L. Völker, S. Preiß, J. Herzberger, H. Frey, K. Heinze, P. Blümler, M. N. Tahir, F. Natalio, W. Tremel*, J. Mater. Chem. B 2016, 4, 7423-7428 "Intrinsic Superoxide Dismutase Activity of MnO Nanoparticles Enhances Magnetic Resonance Imaging Contrast" [DOI: 10.1039/C6TB02078J]

• Prof. Dr. F. Rainer Winter, Department of Inorganic Chemistry, University of Konstanz
  D. Siebler, M. Linseis, T. Gasi, L. M. Carrella, R. F. Winter, C. Förster, K. Heinze*, Chem. Eur. J. 2011, 17, 4540-4551 "Oligonuclear Ferrocene Amides: Mixed-valent Peptides and Potential Redox-switchable Foldamers" [DOI: 10.1002/chem.201002101]

• Prof. Dr. Rudof Zentel, Institute of Organic Chemistry, University of Mainz
  L. zur Borg, A. L. Domanski, A. Breivogel, M. Bürger, R. Berger, K. Heinze*, R. Zentel*, J. Mater. Chem. C 2013, 1, 1223-1230 "Light-Induced Charge Separation in a Donor-Chromophore-Acceptor Nanocomposite Poly[TPA-Ru(tpy)₂]@ZnO" [DOI:10.1039/C2TC00535B]