2020-2023

Publications 2023

224) M. Schulz, M. Karnahl, N. Sinha, L. Thomisch, O. S. Wenger, K. Heinze, B. Dietzek-Ivanšić, S. Tschierlei,
submitted.
Trendbericht Photochemie: Edelmetallfreie Koordinationsverbindungen als Photosensibilisatoren in der Energieumwandlung und Katalyse - Ausgewählte Highlights jenseits von Ru und Ir

223) P. Sikora, R. Naumann, C. Förster*, K. Heinze*,
Chem. Sci. 2023, accepted.
Excited State Energy Landscape of Phosphorescent Group 14 Complexes
[DOI: 10.1039/D2SC06984A]
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222) S. Sittel, A. C. Sell, K. Hofman, C. Wiedemann, J. P. Nau, C. Kerzig*, G. Manolikakes*, K. Heinze*,
Chem. Cat. Chem. 2023, in press.
Visible-Light Induced Fixation of SO2 into Organic Molecules with Polypyridine Chromium(III) Complexes
[DOI: 10.1002/cctc.202201562]
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221) C. Wang, K. Ebel, K. Heinze, U. Resch-Genger*, I. Bald*,
Chem. Eur. J. 2023, accepted.
Quantum Yield of DNA Strand Breaks under Photon Excitation of a Molecular Ruby
[DOI: 10.1002/chem.202203719]
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220) M. Dorn, D. Hunger, C. Förster, R. Naumann, J. van Slageren*, K. Heinze*,
Chem. Eur. J. 2023, in press.
Towards Luminescent Vanadium(II) Complexes with Slow Magnetic Relaxation and Quantum Coherence
[DOI: 10.1002/chem.202202898]
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219) W. R. Kitzmann, K. Heinze*,
Angew. Chem. Int. Ed. 2023, in press.
Charge-Transfer and Spin-Flip States: Thriving as Complements
[DOI: 10.1002/ange.202213207][DOI: 10.1002/anie.202213207]
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Publications 2022

218) L. Stein, C. Wang, C. Förster, U. Resch-Genger, K. Heinze*,
Dalton Trans. 2022, 51, 17664-17670.
Bulky Ligands protect Molecular Ruby from Oxygen Quenching
[DOI: 10.1039/d2dt02950b]
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217) C. Förster*, K. Heinze*,
Chem. Phys. Rev. 2022, 3, 041302.
Bimolecular Reactivity of 3d Metal-Centered Excited States (Cr, Mn, Fe, Co)
[DOI: 10.1063/5.0112531]
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216) J. Moll, R. Naumann, L. Sorge, C. Förster, N. Gessner, L. Burkhardt, N. Ugur, P. Nuernberger, W. Seidel, C. Ramanan, M. Bauer, K. Heinze*,
Chem. Eur. J. 2022, e202201858.
Pseudo-octahedral Iron(II) Complexes with Near-degenerate Charge Transfer and Ligand Field States at the Franck-Condon Geometry
[DOI: 10.1002/chem.202201858]
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215) C. Schreck, J. Weihermüller, P. Thoma, S. Rosenfeldt, M. Drechsler, C. Förster, K. Heinze, G. Hörner, B. Weber*,
Eur. J. Inorg. Chem. 2022, e202200341.
Solvent-dependent self-assembly of an amphiphilic copper(II) complex with bulky head groups
[DOI: 10.1002/ejic.202200341]
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214) N. R. East, C. Förster, L. M. Carrella, E. Rentschler, K. Heinze*,
Inorg. Chem. 2022, 61, 14616–14625.
The full d3–d5 Redox Series of Mononuclear Manganese Complexes: Geometries and Electronic Structures of [Mn(dgpy)2]n+
[DOI: 10.1021/acs.inorgchem.2c01680]
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213) S. D. Waniek, C. Heine, D. Zorn, T. Lieberth, M. Lauck, C. Förster*, Katja Heinze*,
Organometallics 2022, 41, 2050-2058.
Dicobaltocenium amine – proton, electron and H atom transfer
[DOI: 10.1021/acs.organomet.2c00211]
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212) F. Reichenauer, D. Schollmeyer*, K. Heinze,
CSD Communication 2022, CCDC 2169447: Experimental Crystal Structure Determination
TOC=
[DOI: 10.5517/ccdc.csd.cc2bth5v]

211) N. R. East, K. Heinze, D. Schollmeyer*,
CSD Communication 2022, CCDC 2158681: Experimental Crystal Structure Determination
TOC=
[DOI: 10.5517/ccdc.csd.cc2bg8wz]

210) S. Sittel, R. Naumann*, K. Heinze*,
Front. Chem. 2022, 10, 887439.
Molecular Rubies in Photoredox Catalysis
[DOI: 10.3389/fchem.2022.887439]
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209) W. R. Kitzmann, C. Ramanan, R. Naumann, K. Heinze*,
Dalton Trans. 2022, 51, 6519-6525.
Molecular Ruby: Exploring the Excited State Landscape (invited Frontier article)
[DOI: 10.1039/D2DT00569G]
TOC=TOC=
The paper is also highlighted as a cover

208) W. R. Kitzmann*, J. Moll, K. Heinze*,
Photochem. Photobiol. Sci. 2022, 21, 1309–1331.
Spin-Flip Luminescence
[DOI: 10.1007/s43630-022-00186-3]
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207) C. Grundke, R. C. Silva, W. R. Kitzmann, K. Heinze, K. T. de Oliveira*, T. Opatz*,
J. Org. Chem. 2022, 87, 5630-5642.
Photochemical alpha-Aminonitrile Synthesis using Zn Phthalocyanines as Near Infrared Photocatalysts
[DOI: 10.1021/acs.joc.1c03101]
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206) L. Stein, P. Boden, R. Naumann, C. Förster, G. Niedner-Schatteburg, K. Heinze*,
Chem. Commun. 2022, 58, 3701–3704.
The overlooked NIR luminescence of Cr(ppy)3
[DOI: 10.1039/D2CC00680D]
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205) C. Wang, W. R. Kitzmann, F. Weigert, C. Förster, X. Wang, K. Heinze,* U. Resch-Genger*,
ChemPhotoChem 2022, 6, e202100296.
Matrix Effects on Photoluminescence and Oxygen Sensitivity of a Molecular Ruby
[DOI: 10.1002/cptc.202100296]
TOC=
This article was selected as an Editor's Spotlight published in Chemistry Europe, GDCh, and ACES journals.

204) C. Wang, F. Reichenauer, W. R. Kitzmann, C. Kerzig*, K. Heinze*, U. Resch-Genger*,
Angew. Chem. Int. Ed. 2022, 61, e202202238; Angew. Chem. 2022, 134, e202202238.
Efficient Triplet-Triplet Annihilation Upconversion Sensitized by a Chromium(III) Complex via an Underexplored Energy Transfer Mechanism
[DOI: 10.1002/anie.202202238]
TOC=
This study is selected as a hot paper in Angewandte Chemie.

203) J. Moll, C. Förster, A. König, L. M. Carrella, M. Wagner, M. Panthöfer, A. Möller, E. Rentschler, K. Heinze*,
Inorg. Chem. 2022, 61,1659–1671.
Panchromatic Absorption and Oxidation of an Iron(II) Spin Crossover Complex
[DOI: 10.1021/acs.inorgchem.1c03511]
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202) S. D. Waniek, C. Förster*, K. Heinze*,
Eur. J. Inorg. Chem. 2022, e202100905.
Protic ferrocenyl acyclic diamino carbene gold(I) complexes
[DOI: 10.1002/ejic.202100905]
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Publications 2021

201) K. Heinze*,
Nat. Chem. 2021, 13, 926–928.
Made with manganese (News & Views)
[DOI: 10.1038/s41557-021-00785-0]
[ShareIt link]
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200) F. Reichenauer, C. Wang, C. Förster, P. Boden, N. Ugur, R. Báez-Cruz, J. Kalmbach, L. M. Carrella, E. Rentschler, C. Ramanan, G. Niedner-Schatteburg, M. Gerhards, M. Seitz,* U. Resch-Genger*, K. Heinze*,
J. Am. Chem. Soc. 2021, 143, 11843–11855.
Strongly Red-Emissive Molecular Ruby [Cr(bpmp)2]3+ surpasses [Ru(bpy)3]2+
[DOI: 10.1021/jacs.1c05971]
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199) S. T. Hauer, A. P. W. Schneeweis, S. D. Waniek, L. P. Sorge, K. Heinze, T. J. J. Müller*,
Org. Chem. Front. 2021, 8, 5744–5755.
Radical cations and dications of bis[1]benzothieno[1,4]thiazine isomers
[DOI: 10.1039/D1QO00867F]
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198) T. Reuter, A. Kruse, R. Schoch, M. Bauer, S. Lochbrunner, K. Heinze*,
Chem. Commun. 2021, 57, 7541–7544.
Higher MLCT Lifetime of Carbene Iron(II) Complexes by Chelate Ring Expansion
[DOI: 10.1039/D1CC02173G]
TOC=

197) M. Dorn, J. Kalmbach, P. Boden, A. Kruse, C. Dab, C. Reber, G. Niedner-Schatteburg, S. Lochbrunner, M. Gerhards, M. Seitz*, K. Heinze*,
Chem. Sci. 2021, 12, 10780–10790.
Ultrafast and long-time excited state kinetics of an NIR-emissive vanadium(III) complex I: Synthesis, spectroscopy and static quantum chemistry
[DOI: 10.1039/D1SC02137K]
TOC=

196) P. Dierks, A. Kruse, O. S. Bokareva, M. J. Al-Marri, J. Kalmbach, M. Baltrun, A. Neuba, R. Schoch, S. Hohloch, K. Heinze, M. Seitz, O. Kühn, S. Lochbrunner, M. Bauer*,
Chem. Commun. 2021, 57, 6640–6643.
Distinct photodynamics of k-N and k-C pseudoisomeric iron(II) complexes
[DOI: 10.1039/d1cc01716k]
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195) P. Boden, P. Di Martino-Fumo, G. Niedner-Schatteburg, W. Seidel, K. Heinze*, M. Gerhards,
Phys. Chem. Chem. Phys. 2021, 23, 13808–13818.
Transient FTIR spectroscopy after one- and two-colour excitation on a highly luminescent chromium(III) complex
[DOI: 10.1039/D1CP01077H]
TOC=TOC=
The paper is also highlighted as a back cover and selected as a "Hot Article" in the journal Phys. Chem. Chem. Phys..

194) M. Dorn, N. R. East, C. Förster, W. R. Kitzmann, J. Moll, F. Reichenauer, T. Reuter, L. Stein, K. Heinze*,
in press (release 03/2023).
d-d and Charge Transfer Photochemistry of 3d Metal Complexes
in Comprehensive Inorganic Chemistry III (Section Ed. V. W.-W. Yam).
TOC=
For a preview in Reference Module in Chemistry, Molecular Sciences and Chemical Engineering 2022 see [DOI: 10.1016/B978-0-12-823144-9.00063-7]

193) J. Steube, A. Päpcke, O. S. Bokareva, T. Reuter, S. Demeshko, R. Schoch, S. Hohloch, F. Meyer, K. Heinze, O. Kühn, S. Lochbrunner, M. Bauer, submitted.
Janus-type emission of a Cyclometalated Iron(III) complex
[preprint]

192) N. D. Boscher*, G. Bengasi, K. Heinze*,
Chemical Vapour Deposition of Porphyrins
in Applications of Porphyrinoids as Functional Materials
(Ed. H. Lang, T. Rueffer), RSC 2021, chapter 5, pp 121–148.
[DOI: 10.1039/9781839164149-00121]
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Publications 2020

191) K. Heinze*, O. Wenger*,
Inorg. Chem. 2020, 59, 14627–14628.
Light-Controlled Reactivity of Metal Complexes (editorial of the Forum issue)
[DOI: 10.1021/acs.inorgchem.0c02791]
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190) P. Dierks, A. Päpcke, B. Altenburger, O. Bokareva, T. Reuter, K. Heinze, O. Kühn, S. Lochbrunner, M. Bauer*,
Inorg. Chem. 2020, 59, 14746–14761.
Ground and excited state properties of iron(II) complexes linked to organic chromophores
[DOI: 10.1021/acs.inorgchem.0c02039]
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189) J. Kalmbach, C. Wang, Y. You, C. Förster, H. Schubert, K. Heinze*, U. Resch-Genger*, M. Seitz*,
Angew. Chem. 2020, 132, 18966–18970; Angew. Chem. Int. Ed. 2020, 59, 18804–18808.
Near-IR to Near-IR Upconversion Luminescence in Molecular Chromium Ytterbium Salts
[DOI: 10.1002/ange.202007200][DOI: 10.1002/anie.202007200]
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188) G. Zeh, P. Haines, M. E. Miehlich, T. Kienz, A. Neidlinger, R. P. Friedrich, H. G. Özkan, C. Alexiou, F. Hampel, D. M. Guldi, K. Meyer, J. Schatz, K. Heinze, A. Mokhir*,
Organometallics 2020, 39, 3112–3120.
Anticancer Activity of an Electronically Coupled Oligoferrocene
[DOI: 10.1021/acs.organomet.0c00306]
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187) G.Bengasi, L. Quétu, K. Baba, A. Ost, J. P. Cosas Fernandes, P. Grysan, K. Heinze*, N. D. Boscher*,
Eur. J. Inorg. Chem. 2020, 1938–1945.
Constitution and Conductivity of Metalloporphyrin Tapes
[DOI: 10.1002/ejic.202000243]
TOC= TOC=
The paper is also highlighted as a cover in the journal Eurpean Journal of Inorganic Chemistry.

186) J. Moll, C. Wang, A. Päpcke, C. Förster, U. Resch-Genger, S. Lochbrunner, K. Heinze*,
Chem. Eur. J. 2020, 26, 6820–6832.
Green Light Activation of Push-Pull Ruthenium(II) Complexes
[DOI: 10.1002/chem.202000871]
TOC= TOC=
The paper is also highlighted as a cover in the journal Chemistry - A European Journal.

185) C. Förster*, K. Heinze*,
J. Chem. Ed. 2020, 97, 1644–1649.
Preparation and Thermochromic Switching between Phosphorescence and Thermally Activated Delayed Fluorescence of Mononuclear Copper(I) Complexes
[DOI: 10.1021/acs.jchemed.0c00171]
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184) P. M. Becker, C. Förster, L. M. Carrella, P. Boden, D. Hunger, J. van Slageren, M. Gerhards, E. Rentschler, K. Heinze*,
Chem. Eur. J. 2020, 26, 7199–7204.
Spin Crossover and Long-lived Excited States in a Reduced Molecular Ruby
[DOI: 10.1002/chem.202001237]
TOC=

183) P. Veit, S. Seibert, C. Förster*, K. Heinze*,
Z. Anorg. Allg. Chem. 2020, 646, 940–947.
Unexpected C-C Bond Formation with a Ferrocenyl Fischer Carbene Complex
[DOI: 10.1002/zaac.201900350]
TOC=

182) M. Dorn, J. Kalmbach, P. Boden, A. Päpcke, S. Gómez, C. Förster, F. Kuczelinis, L. M. Carrella, L. Büldt, N. Bings, E. Rentschler, S. Lochbrunner, L. González, M. Gerhards*, M. Seitz*, K. Heinze*,
J. Am. Chem. Soc. 2020, 142, 7947–7955.
A vanadium(III) complex with blue and NIR-II spin-flip luminescence in solution
[DOI: 10.1021/jacs.0c02122]
TOC=

181) C. Förster*, K. Heinze*,
Chem. Soc. Rev. 2020, 49, 1057–1070.
Photophysics and photochemistry with Earth-abundant metals – fundamentals and concepts
[DOI: 10.1039/c9cs00573k]
TOC=TOC=
The review is also highlighted as a cover in the journal Chemical Society Reviews.

180) G. Bengasi, J. Desport, K. Baba, J. Cosas Fernandes, O. De Castro, K. Heinze*, N. Boscher*,
RSC Adv. 2020, 10, 7048–7057.
Molecular Flattening Effect to Enhance the Conductivity of Fused Porphyrin Tapes Thin Films
[DOI: 10.1039/C9RA09711B]
TOC=

179) S. Gharaati, C. Wang, C. Förster, F. Weigert, U. Resch-Genger*, K. Heinze*,
Chem. Eur. J. 2020, 26, 1003–1007.
Triplet-Triplet Annihilation Upconversion in a MOF with Acceptor-filled Channels
[DOI: 10.1002/chem.201904945]
TOC=TOC=
The paper is also highlighted as a cover in the journal Chemistry - A European Journal.